tert-Butyloxycarbonyl-Leucine-Phenylalanine-Alanine-α,β‐dehydrophenylalanine-Leucine-Methyl ester
Sequence: Boc-L-F-A-ΔF-L-OMe
Core Sequence: L-F-A-ΔF-L
R Value: 0.044
Residue Involved: Leucine | Phenylalanine | Alanine | α,β‐dehydrophenylalanine | Leucine
Conformation: Right-handed 3(10) helical
| Name of Peptide: | tert-Butyloxycarbonyl-Leucine-Phenylalanine-Alanine-α,β‐dehydrophenylalanine-Leucine-Methyl ester |
| Sequence: | Boc-L-F-A-ΔF-L-OMe |
| Core Sequence: | L-F-A-ΔF-L |
| Sequence Length: | 5 |
| Molecular Weight (amu): | 721.9 |
| Molecular Formula: | C39-H55-N5-O8 |
| R Value: | 0.044 |
| N-Terminal Modification: | tert-Butyloxycarbonyl |
| C-Terminal Modification: | Methyl ester |
| Conformation: | Right-handed 3(10) helical |
| Method: | X - Ray Diffraction |
| Core Residue Involved | Phi | Psi | Omega |
|---|---|---|---|
| Leucine | -59.5 | -38.8 | 174.0 |
| Phenylalanine | -66.5 | -19.5 | 177.8 |
| Alanine | -66.4 | -15.1 | 172.3 |
| α,β‐dehydrophenylalanine | -67.3 | -16.1 | -177.4 |
| Leucine | -93.0 | -164.5 | Unmeasured |