tert-Butyloxycarbonyl-Glycine-α,β‐dehydrophenylalanine-Leucine-α,β‐dehydrophenylalanine-Alanine-Methylamide
Sequence: Boc-G-ΔF-L-ΔF-A-NHCH3
Core Sequence: G-ΔF-L-ΔF-A
R Value: 0.038
Residue Involved: Glycine | α,β‐dehydrophenylalanine | Leucine | α,β‐dehydrophenylalanine | Alanine
Conformation: Right-handed 3(10) helical
| Name of Peptide: | tert-Butyloxycarbonyl-Glycine-α,β‐dehydrophenylalanine-Leucine-α,β‐dehydrophenylalanine-Alanine-Methylamide |
| Sequence: | Boc-G-ΔF-L-ΔF-A-NHCH3 |
| Core Sequence: | G-ΔF-L-ΔF-A |
| Sequence Length: | 5 |
| Molecular Weight (amu): | 662.793 |
| Molecular Formula: | C35-H46-N6-O7 |
| R Value: | 0.038 |
| N-Terminal Modification: | tert-Butyloxycarbonyl |
| C-Terminal Modification: | Methylamide |
| Conformation: | Right-handed 3(10) helical |
| Method: | X - Ray Diffraction |
| Core Residue Involved | Phi | Psi | Omega |
|---|---|---|---|
| Glycine | -59.7 | -30.5 | 177.8 |
| α,β‐dehydrophenylalanine | -57.5 | -27.7 | 175.4 |
| Leucine | -71.2 | -15.4 | 172.8 |
| α,β‐dehydrophenylalanine | -58.3 | -17.9 | 176.7 |
| Alanine | -79 | 7.1 | 173.4 |